The PNG color problem
Mike Gale found this great link on PNG's and color issues. I've noticed color discrepancies myself, mainly by noticing that the color of some PNG images was showing differently in different browsers and also potentially differing against the same image saved as GIFs and JPGs.
The Sad Story of PNG Gamma “Correction”
The Sad Story of PNG Gamma “Correction”
There is no way of making PNG images that match CSS colors in all PNG-supporting browsers. This reduces the usefulness of the otherwise excellent image format. If the image colors and the colors defined in a style sheet need to match, it is safer to use GIF or JPEG. If you want to use PNG and don’t care about older browser versions (pre-Tiger Safari in particular), the best course of action is removing all the color space information from the PNG files. If you only want a match with the background color, you could make the background a PNG image as well.